Why Ethanol Cannot Be Distilled Above 96%
Ethanol cannot be distilled above 95-96% ethanol because it forms an azeotrope with water. At this point, the liquid and vapor have the same composition, making distillation impossible to separate. Even with higher heat, the purity will not increase. Industries requiring near-100% ethanol use additional drying methods such as molecular sieves, special distillation with added chemicals, or vacuum distillation. These techniques break the azeotrope and produce anhydrous ethanol for chemical, industrial, and laboratory use.
